Search results for "Ion cyclotron resonance spectrometry"
showing 6 items of 6 documents
Ammonium ion mediated resorcarene capsules: ESI-FTICRMS study on gas-phase structure and ammonium ion affinity of tetraethyl resorcarene and its per-…
2003
AbstractThe ammonium ion binding affinities of tetraethyl resorcarene (1) and its per-methylated derivative (2) were studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Ten different ammonium ions were tested as guests for the resorcarenes. A strong tendency for complex formation was observed with all ammonium ions of size and charge distribution suitable for noncovalent interactions with the cavities of the resorcarene hosts 1 and 2. Although differences in ammonium ion affinities were observed between 1 and 2 due to the dissimilar conformations, the overall tendency was that increase in the degree of substitution and the length of ca…
Theory of quadrupole detection fourier transform-ion cyclotron resonance
1991
Abstract The theoretical basis of the recently introduced quadrupole detection Fourier transform-ion cyclotron resonance technique is developed by use of the concept of image charges induced in the detection electrodes. The appearance of resonances at frequencies 2ω+, 2ω−, (ω+ + ω−) and (ω+ − ω−) is explained. The new method is compared with the standard (dipole) detection scheme. Techniques are suggested allowing the simultaneous determination of all resonance frequencies ω+ (perturbed, or reduced, cyclotron frequency), ω− (magnetron frequency) and ωz (trapping frequency).
Instabilities of an electron cloud in a Penning trap
2003
We have measured the storage instabilities of electrons in a Penning trap at low magnetic fields. These measurements are carried out as a function of the trapping voltage, for different magnetic fields. It is seen that these instabilities occur at the same positions when the trapping voltage is expressed as a percentage of the maximum voltage, given by the stability limit. The characteristic frequencies at which these instabilities occur, obey a relation that is given by n zω z + n +ω + + n -ω - = 0, where ω z, ω + and ω - are the axial, perturbed cyclotron and the magnetron frequencies of the trapped electrons respectively, and the n's are integers. The reason for these instabilities are a…
Alkali metal mediated resorcarene capsules: An ESI-FTICRMS study on gas-phase structure and cation binding of tetraethyl resorcarene and its per-meth…
2002
AbstractElectrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) with additional ab initio calculations were used to examine the alkali metal cation binding selectivity (i.e., molecular recognition) and host properties of tetraethyl resorcarene (1) and its per-methylated derivative (2). The significance of intramolecular hydrogen bonding for the crown conformation was demonstrated. The presence of intramolecular flip-flop hydrogen bonding in 1 was confirmed both with calculations and in ND3-exchange experiments. All the alkali metal cations formed host–guest complexes by docking inside the cavity of the host. Complexation with the larger cations, esp…
Individual and center-of-mass resonances in the motional spectrum of an electron cloud in a Penning trap
2002
We have examined experimentally the motional spectrum of an electron cloud confined in a Penning trap. When the axial oscillation is excited by a radio frequency field the resonance exhibits a double structure. Both components depend differently on the number of trapped electrons and have different shape and width. We conclude that one of them corresponds to the excitation of the individual electrons while the other is the center-of-mass mode of the cloud. The threshold behaviour of the center-of-mass resonance suggests that it is a parametric instability of a Mathieu type equation of motion.
Mass spectrometric study of oligourea macrocycles and their anion binding behavior
2009
Two series, one of tris-urea macrocycles and another of hexakis-urea macrocycles, are examined by (tandem) Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry with respect to their fragmentation patterns and anion binding properties. All macrocycles are based on two different building blocks, one of which is a very rigid xanthene unit and the other one is a more flexible diphenyl ether. The composition and the sequence of these units thus determine their flexibility. During the fragmentation of deprotonated oligourea macrocycles in the gas phase, one urea N-CO bond is cleaved followed by a scrambling reaction within the macrocycle structure. Consequently, fragments are obser…